Maitake, Hen of the Woods · 2009 · Research Support, Non U.S. Gov'T
Medium relevanceAn unambiguous structural elucidation of a 1,3-beta-D-glucan obtained from liquid-cultured Grifola frondosa by solution NMR experiments.
Grifola frondosa
Key points
- Grifolan LE (GRN-LE), a purified beta-D-glucan, which is obtained from liquid-cultured Grifola frondosa, exhibits various biological activities, including antitumor effects
- Significant progress has been made in the study of these effects
- However, an unambiguous structural characterization of GRN-LE using NMR spectroscopy has not been carried out as yet
- It is well accepted that the biological effects of a beta-glucan depend on its primary structure, conformation, and molecular weight
- In the present study, we unambiguously elucidate the primary structure of GRN-LE using NMR spectroscopy
- The data presented here reveal that GRN-LE comprises a 1,3-beta-D-glucan backbone with a single 1,6-beta-D-glucosyl side branching unit on every third residue
Metadata-grounded summary
Citation abstract
Grifolan LE (GRN-LE), a purified beta-D-glucan, which is obtained from liquid-cultured Grifola frondosa, exhibits various biological activities, including antitumor effects. Significant progress has been made in the study of these effects. However, an unambiguous structural characterization of GRN-LE using NMR spectroscopy has not been carried out as yet. It is well accepted that the biological effects of a beta-glucan depend on its primary structure, conformation, and molecular weight. In the present study, we unambiguously elucidate the primary structure of GRN-LE using NMR spectroscopy. The data presented here reveal that GRN-LE comprises a 1,3-beta-D-glucan backbone with a single 1,6-beta-D-glucosyl side branching unit on every third residue.
Citation
Tada R, Adachi Y, Ishibashi K, Ohno N (2009). An unambiguous structural elucidation of a 1,3-beta-D-glucan obtained from liquid-cultured Grifola frondosa by solution NMR experiments. Carbohydrate research https://doi.org/10.1016/j.carres.2008.11.005 PMID: 19084824
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